If you are under 65 during the entire tax year, you will only be able to split the payments you directly receive from a registered pension plan. If you are older then you can split your pension income.
Tax on split income (TOSI) applies to certain types of income of a child born in 2005 or later, and amounts received by adult individuals from a related business. Where TOSI applies, the disability tax credit, dividend tax credit and foreign tax credit can be used to reduce the individual's tax payable for the year.
Here is a great TurboTax article to help you: How do I split my pension income with my spouse?
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